$ $ Database for In-Pb from J.P. Nabot 1986 $ $ J.P. Nabot, PhD Thesis, Grenoble, 1986. $ $ Dataset created 2016.02.21 by Bengt Hallstedt. $ 2021.01.17: Modified for use with GES6. $ $ ------------------------------------------------------------------------------ TEMP-LIM 298.15 6000.00 ! $ $ELEMENT NAME REF. STATE ATOMIC MASS H298-H0 S298 ! $ ELEMENT VA VACUUM 0.0 0.0 0.0 ! ELEMENT IN TETRAGONAL_A6 114.82 6610.0 57.65 ! ELEMENT PB FCC_A1 207.2 6870. 64.80 ! $ ------------------------------------------------------------------------------ $ Phase definitions $ PHASE LIQUID:L % 1 1 ! CONST LIQUID:L : IN PB : ! $ $ Fcc (cF4, Fm-3m) and MeX (cF8, Fm-3m) $ PHASE FCC_A1 %A 2 1 1 ! CONST FCC_A1 : IN PB : VA : ! $ $ Bcc (cI2, Im-3m) $ PHASE BCC_A2 %B 2 1 3 ! CONST BCC_A2 : IN PB : VA : ! $ $ Hcp (hP2, P6_3/mmc) and Me2X (NiAs-type, hP4, P6_3/mmc, B8_1) $ PHASE HCP_A3 %A 2 1 0.5 ! CONST HCP_A3 : IN PB : VA: ! $ $ Prototype In (tI2, I4/mmm) $ PHASE TETRAGONAL_A6 % 1 1 ! CONST TETRAGONAL_A6 : IN% PB : ! $ $ Prototype In (tI2, I4/mmm), beta-InSn $ PHASE TET_ALPHA1_A6 % 1 1 ! CONST TET_ALPHA1_A6 : IN PB : ! $ ------------------------------------------------------------------------------ $ Defaults $ DEFINE-SYSTEM-DEFAULT ELEMENT 2 ! DEFAULT-COM DEFINE_SYSTEM_ELEMENT VA ! TYPE-DEF % SEQ * ! TYPE-DEF A GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -3 0.28 ! TYPE-DEF B GES AMEND_PHASE_DESCRIPTION @ MAGNETIC -1 0.4 ! FUNCTION ZERO 298.15 0; 6000 N ! FUNCTION UN_ASS 298.15 0; 6000 N ! FUNCTION R 298.15 +8.31451; 6000 N ! $ ------------------------------------------------------------------------------ $ Element data $ ------------------------------------------------------------------------------ $ In $ $ FCC_A1 and TET_ALPHA1 revised in unary 4.1 $ BCT_A5 and RHOMBOHEDRAL_A7 added in unary 4.1 $ TET_ALPHA1 revised in unary 5.0 (using the value from 99Ans) $ DHCP added in unary 5.0 $ $ There is quite a bit of confusion about TET_ALPHA1_A6. The structure is $ the same as In (TETRAGONAL_A6), but with a different (presumably) c/a ratio. $ TET_ALPHA1_A6 is present in Bi-In, In-Pb and In-Sn (possibly more). Between $ the TETRAGONAL_A6 (In-ss) and TET_ALPHA1_A6 there is a narrow two-phase $ region. In each system a different G(TET_ALPHA1_A6,IN) lattice stability $ was used. $ In 91Din a value from an unpublished revision of the Bi-In system by $ P.-Y. Chevalier 1990 is included. In SGTE Unary V 4.4 a value from 98Boa $ for the In-Pb system is included. 98Boa treated the TET_ALPHA1_A6 $ phase in Bi-In and In-Pb as two different phases and used the lattice $ stability from 88Che0 for the Bi-In branch of this phase. Finally, SGTE $ unary V 5.0 uses a value from an unpublished evaluation by 99Ans of the $ In-Sn system. Due to the close proximity of the TETRAGONAL_A6 and $ TET_ALPHA1_A6 phases in these systems, any change of lattice stability $ will cause a distortion of the phase diagram and require reoptimisation. $ $ The DHCP phase is labelled D0_24 in 03Liu and alpha-prime in 92Ans. The $ phase is present between the fcc and hcp phases in the Au-Sn and Au-In $ systems. $ PAR G(TETRAGONAL_A6,IN),, +GHSERIN; 3800 N 91Din ! PAR G(FCC_A1,IN:VA),, +GHSERIN+162.061; 3800 N 98Boa ! $PAR G(FCC_A1,IN:VA),, +GHSERIN+123-0.1988*T; 3800 N 91Din ! PAR G(BCC_A2,IN:VA),, +GHSERIN+800-0.8*T; 3800 N 91Din ! PAR G(HCP_A3,IN:VA),, +GHSERIN+533-0.6868*T; 3800 N 91Din ! $PAR G(DHCP,IN),, +GHSERIN+520-0.384*T; 3800 N 92Ans ! $PAR G(TET_ALPHA1_A6,IN),, +GHSERIN+123-0.1988*T; 3800 N 99Ans ! $PAR G(TET_ALPHA1_A6,IN),, +GHSERIN+0.31*T; 3800 N 98Boa ! PAR G(TET_ALPHA1_A6,IN),, +GHSERIN+193-0.16479*T; 3800 N 91Din ! $PAR G(TET_ALPHA1_A6,IN),, +GHSERIN-33+0.16*T; 3800 N 88Che0 ! $PAR G(BCT_A5,IN),, +GHSERIN $ +5040.87-3.33969*T; 3800 N 99Ans ! $PAR G(RHOMBOHEDRAL_A7,IN),, +GHSERIN+4184; 3800 N 88Che0 ! PAR G(LIQUID,IN),, +GLIQIN; 3800 N 91Din ! $ FUNCTION GHSERIN 298.15 -6978.89+92.338115*T-21.8386*T*LN(T) -0.00572566*T**2-2.120321E-06*T**3-22906*T**(-1); 429.75 Y -7033.516+124.476588*T-27.4562*T*LN(T) +5.4607E-04*T**2-8.367E-08*T**3-211708*T**(-1)+3.53116E+22*T**(-9); 3800.00 N ! FUNCTION GLIQIN 298.15 +3282.092-7.63686*T+GHSERIN-5.59058E-20*T**7; 429.75 Y +3283.706-7.640804*T+GHSERIN-3.53116E+22*T**(-9); 3800.00 N ! $ ------------------------------------------------------------------------------ $ Pb $ $ RHOMBOHEDRAL_A7 and TETRAGONAL_A6 added in unary 3.0 $ RHOMBOHEDRAL_A7, TETRAGONAL_A6 and TET_ALPHA1_A6 revised in unary 4.1 $ RHOMBO_A10 added in unary 5.0 $ PAR G(FCC_A1,PB:VA),, +GHSERPB; 2100 N 91Din ! PAR G(BCC_A2,PB:VA),, +GHSERPB+2400-1.1*T; 2100 N 91Din ! PAR G(HCP_A3,PB:VA),, +GHSERPB+300+T; 2100 N 91Din ! PAR G(BCT_A5,PB),, +GHSERPB+489+3.52*T; 2100 N 91Din ! $PAR G(TETRAGONAL_A6,PB),, +GHSERPB+4493.235; 2100 N 98Boa ! PAR G(TETRAGONAL_A6,PB),, +GHSERPB+473.23+3.5531*T -0.0396834*T*LN(T)+2.1489E-05*T**2; 2100 N 96SGUN ! $PAR G(TET_ALPHA1_A6,PB),, +GHSERPB $ +1903.3-2.0602*T; 2100 N 98Boa ! PAR G(TET_ALPHA1_A6,PB),, +GHSERPB+183.2+0.45314*T -0.0396834*T*LN(T)+2.149E-06*T**2; 2100 N 91Din ! $PAR G(RHOMBOHEDRAL_A7,PB),, +GHSERPB+300+T; 2100 N 99SGUN ! $PAR G(RHOMBOHEDRAL_A7,PB),, +GHSERPB+4900+3.52*T; 2100 N 96SGUN ! $PAR G(RHOMBO_A10,PB),, +GHSERPB+10; 2100 N 09SGUN ! PAR G(LIQUID,PB),, +GLIQPB; 2100 N 91Din ! $ FUNCTION GHSERPB 298.15 -7650.085+101.700244*T-24.5242231*T*LN(T) -0.00365895*T**2-2.4395E-07*T**3; 600.61 Y -10531.095+154.243182*T-32.4913959*T*LN(T) +0.00154613*T**2+8.05448E+25*T**(-9); 1200.00 Y +4157.616+53.139072*T-18.9640637*T*LN(T) -0.002882943*T**2+9.8144E-08*T**3-2696755*T**(-1)+8.05448E+25*T**(-9); 2100.00 N ! FUNCTION GLIQPB 298.15 +4672.124-7.750683*T+GHSERPB-6.019E-19*T**7; 600.61 Y +4853.137-8.067136*T+GHSERPB-8.05448E+25*T**(-9); 2100.00 N ! $ ------------------------------------------------------------------------------ $ Binary system $ $ J.P. Nabot, PhD Thesis, Grenoble, 1986. $ $ Checked at 6000 K. $ PAR L(LIQUID,IN,PB;0),, +3749.6-0.6897*T;,, N 86Nab ! PAR L(LIQUID,IN,PB;1),, +348.2-0.8906*T;,, N 86Nab ! $ PAR L(FCC_A1,IN,PB:VA;0),, +4443-1.50763*T;,, N 86Nab ! PAR L(FCC_A1,IN,PB:VA;1),, +490.4-0.71576*T;,, N 86Nab ! $ PAR L(TETRAGONAL_A6,IN,PB;0),, +2539.3;,, N 86Nab ! PAR L(TETRAGONAL_A6,IN,PB;1),, -174.4;,, N 86Nab ! $ PAR L(TET_ALPHA1_A6,IN,PB;0),, +3734.9;,, N 86Nab ! PAR L(TET_ALPHA1_A6,IN,PB;1),, -416.1;,, N 86Nab ! $ $ Metastable $ PAR L(BCC_A2,IN,PB:VA;0),, +4443-1.50763*T;,, N Same ! PAR L(BCC_A2,IN,PB:VA;1),, +490.4-0.71576*T;,, N Same ! $ PAR L(HCP_A3,IN,PB:VA;0),, +4443-1.50763*T;,, N Same ! PAR L(HCP_A3,IN,PB:VA;1),, +490.4-0.71576*T;,, N Same ! $ ------------------------------------------------------------------------------ $ ASSESSED_SYSTEM IN-PB(TDB -* +LIQUID +FCC_A1 +TETRA_A6 +TET_ALPHA1 ;P3 TMM:300/1000 *) ! $ $ LIST-OF-REFERENCE NUMBER SOURCE Null 'Unknown source' Same 'Same or similar interaction as in the corresponding stable phase' COST 'COST 507 database' 86Nab 'J.P. Nabot, PhD Thesis, Grenoble, 1986; In-Pb' 88Che0 'P.-Y Chevalier, Calphad, 12, 383-92(1988) SGTE unary database V.4.1, 1999; In' 89Fec 'H.J. Fecht, M.X. Zhang, Y.A. Chang, J.H. Perepezko, Metall. Trans. A, 20A, 795-803(1989); Sn' 91Din 'A.T. Dinsdale, Calphad, 15, 317-425(1991).' 92Ans 'I. Ansara, J.-Ph. Nabot, Calphad, 16, 13-18(1992), SGTE unary database V.5.0, 2009; In' 96SGUN 'SGTE unary database V.3.0, 1996.' 98Boa 'D. Boa, I. Ansara, Thermochim. Acta, 314, 79-86(1998), SGTE unary database V.4.1, 1999; In, Pb' 99Ans 'I. Ansara, S.G. Fries, H.L. Lukas, unpublished, 1999, SGTE unary database V.5.0, 2009; In, Sn' 99SGUN 'SGTE unary database V.4.1, 1999.' 03Din 'A.T. Dinsdale, modification of TET_ALPHA1_A6, 2003; In-Pb, In-Pb-Sn' 09SGUN 'SGTE unary database V.5.0, 2009.' !